Dynamic Modelling of a PEM Electrolyser and Metal Hydride Hydrogen Storage System
Michele Bolognese, Matteo Testi, Paolo Piras, Giulia Bonamigo, Erika Michela Dematteis, Paola Rizzi, Marcello Baricco
Renewable deployment requires hydrogen storage decoupling production from demand, and metal hydride systems offer a safe, low-pressure, high-density option. Within the EU REMEDHYS project, a solid-state storage system based on an intermetallic alloy produced from recycled European metals is coupled to a 2 MW proton exchange membrane electrolyser. This paper presents a modular, equation-based Modelica model of the balance of plant of both subsystems, comprising eleven control loops, measured pressure-composition isotherms and a pseudo-twodimensional discretisation of the hydride bed. A 2 MW to 1 MW load step, a full absorption-desorption cycle, a sensitivity analysis and a coupled scenario feeding twenty cassettes are simulated. The hydrogen delivered per cycle falls from 4281 to 3292 g as the delivery pressure rises from 1 to 5 bar and doubles between 50 and 70 ◦C. Coupled to the electrolyser, a cassette charges in 6.6 h and stops discharging at a state of charge of 0.24, limited by the alloy equilibrium pressure.
Hydrogen & Heat
Energy (R2002)